PA条件不成立时GEE方法中的检验问题

边际回归模型和与此有关的广义估计方程(GEE)在纵向数据分析中得到了广泛的应用. Pepe和Anderson在1994指出在边际模型和GEE方法的应用中必须满足一个重要条件, 即PA条件. 如果该假定不能满足, 可能得不到相合估计, 由此进行的统计推断的效率可能不高. 本文通过简单的AR(1)模型, 在理论上和数值模拟上讨论了PA条件对基于广义估计方程方法所作的关于回归系数的检验的影响. 由于PA条件不成立, 回归系数的GLS估计不再是渐近无偏的, 构造的Wald和Score统计量的分布不再是中心卡方分布, 从而对于检验的效率也产生了严重影响.     

中国东中西部城市房价波动的涟漪效应——以中国东中西部代表的九城市为例

针对中国东中西部城市房价波动的是否存在涟漪效应的问题,提出综合运用格兰杰因果检验、协整一体化及二阶段检验法,即弗里德曼非参数秩排序检验方法和商业周期定点分析方法来检验分析自2005年7月至2010年3月东中西九城市房屋销售价格的月度数据进行实证分析,结果表明:(1)认为中国九城市房价波动存在涟漪效应,可划分为三个层级:东部的上海、深圳、杭州为第一层级;中部的武汉、合肥、太原为第二层级;西部的成都、西安、兰州为第三层级。(2)房价波动的涟漪效应从东部城市开始,传向中部城市,最后向西部城市传递。结论为东部城市的房价波动为主要调控对象,关注中部城市房价,同时避免西部城市房价出现意外波动。建议为对各个层级城市的房价制定差别性的调控政策,能够更有效地对整个房价体系的波动进行控制。     

Structure Elucidation of Two Acetylated Derivatives of Oligomycin A

Partial acetylation of oligomycin A (1) resulted in the formation of 5,9, 33-tri-O-acetyl (2) and 5,9,13,33-tetraacetyl (3) derivatives whose structures have been established through complete assignments of their H and ¹³C NMR spectra. These derivatives were devoid of inhibitory activity when tested on Aspergillus niger spores.     

非线性兰姆波在阶梯板中传播的有限元仿真

在非线性兰姆波检测中,累积二次谐波是重要的检测信号.该文利用有限元法仿真了非线性兰姆波在阶梯板中的产生和传播过程,通过二维离散傅里叶变换分析了兰姆波的传播模态和各个模态通过波导横截面的能流大小,给出了各个模态在阶梯板中的反射、透射系数,总结了其随阶梯板厚度的变化规律.研究发现,随着台阶增高,散射效应使得兰姆波更难入射波...     

Nondestructive Quantitative Analysis of Analgini Powder Pharmaceutical by Near-Infrared Spectroscopy and Artifical Neural Network Technique

ABSTRACT

This paper demonstrates the usefulness of near-infrared (NIR) spectra and artificial neural network (ANN) in nondestructive quantitative analysis of pharmaceuticals. Real data sets from near-infrared reflectance spectra of analgini powder pharmaceutical were used to build up an artificial neural network to predict unknown samples. The parameters affecting the network were discussed. A new network evaluation criterion, the degree of approximation, was employed. The overfitting was discussed. Owing to the good nonlinear multivariate calibration nature of ANN, the predicted result was reliable and precise. The relative error of unknown samples was less than 2.5%     

Nondestructive Synchrotron Radiation X-Ray Fluorescence Imaging of Trace Elements on Methylmercury and Selenium Administered Guinea Pigs

Abstract

The dynamics of the brain distributions of Hg, Zn, Cu and Se in guinea pigs exposed to methylmercury and selenium were examined by X-ray fluorescence imaging utilizing synchrotron radiation.

Male Hartley guinea pigs were administered methyl mercury chloride and/or sodium selenite every day for ten days (s.c. 3mg as Hg/kg/day, mole ratio Hg:Se=1:1). Two dimensional distributions of Hg, Zn, Cu and Se in guinea pig brain were observed by nondestructive X-ray fluorescence imaging. Using the     

微波适用塑料食品保鲜膜/袋组分的总迁移量测定方法的对比

从超市选购15种微波适用塑料食品保鲜膜或袋作为样品,应用EN 1186-13-2002和GB/T 5009.156-2003两种标准方法中所述方法对样品在存放脂肪类食品时其组分迁移至食品中的总量做了测定。试验中用橄榄油和正己烷作为模拟食品,GB/T标准方法的检测结果表明:15种样品均属合格产品,而EN标准方法的检测结果表明在此15种样品中有4种属不合格,其合格率为73.3%。为探究两种方法所得结果存在差异的原因,采用红外光谱法(IR)、差示扫描量热法(DSC)及热失重法(TG)3种测试方法对上述样品作进一步研究。结果发现不合格的样品中含填料较高。此外,EN标准方法中所采用的样品预处理条件与实际使用情况更为接近。     

非球面光学元件的面形检测技术

介绍了非球面各加工阶段的面形检测技术及其最新进展,重点介绍了非球面精密抛光期的面形检测技术,并对其中的非零位子孔径拼接干涉检测法和部分补偿法进行了详细阐述,提出了适用于大口径、深度非球面面形检测的组合干涉法的概念。概述了近年来受到关注的自由曲面非球面的发展和检测技术现状,展望了非球面检测技术的发展趋势。     

光束整形系统异形元件的研制

为了实现非球柱面镜的高精度加工,解决这一领域面临的难题,对非球柱面镜的加工和检测方法进行了深入的研究。采用古典与现代制造技术相结合的方法,研制了用于光束整形的异形元件,该异形元件是由非球柱面镜和柱面镜组成。针对非球柱面镜面型难以控制的问题,给出了独特的抛光模设计。结果表明：经过轮廓仪检测面型精度为0.848 7 μm,达到了图纸精度,满足了光学元件的使用要求。     

Polyspectral technique for the analysis of stress-waves characteristics and species recognition in wood veneers

In this work a simple technique to obtain information about the species of wood samples using stress-wave sounds in the audible range is presented. However, spectra of wood sounds generated by pendulum impact are very complex and feature extraction for classification purposes is very difficult. Polyspectral techniques have been successfully applied to several problems from radar pattern recognition to medical signal processing. Following this approach, convolution of four different sound impacts has been done. This permits to extract clear polyspectral features suitable for wood species recognition with possible applications to both human assisted and automatic wood identification systems with minimal intersample variability. Results indicate that using this technique only the two most intense polyspectral peaks are enough for species recognition.